" k# G6 `! B; h8 L, U 海洋有机地球化学实验室II
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) h# A) x- ]- @7 D. p 课题组负责人及老师介绍:
( y& Y1 i; h' Y& K9 | \: \/ v 李先国 教授,博士生导师
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冯丽娟教授,硕士生导师
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$ y5 X/ s) v% f1 T. S- B 张大海 副教授,硕士生导师
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姚硕 讲师 3 _4 E" w+ i N6 y# H
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; G& S3 ]# k0 f; I/ q 课题组研究领域与方向  4 ]* i4 m; |( O# r' b, N$ ]2 ~0 q7 S
目前课题组主要开展四个方向的研究,分别是: - ]1 B2 ^* f+ @7 C# C0 F& k- ?. V
(一)、陆源有机物及其沉积记录:以木质素、正构烷烃、脂质等为特征生物标志物,研究其在海洋中的沉积记录及其环境地球化学意义。 : j5 ^- x/ Q, X
(二)、现代有机污染物及其转化机理:通过实验室模拟实验中降解中间产物或/和代谢产物的分析、稳定同位素分馏效应的测定以及理论计算,与现场测定结果相结合,研究典型有机污染物在环境中的来源、分布及其光降解和生物降解机理,结合定量构效关系研究,评价其生态风险。目前已经开展的污染物研究包括多环芳烃(PAH)、多氯联苯(PCB)、多溴联苯醚(PBDE)、德克隆(DP)、塑化剂(PAES)、烷基酚(NP和OP)、微塑料(MP)等。 / t( G; \6 L( V+ d8 z. ^
(三):海洋资源化学:通过分析海洋来源物质的成分、结构,确定其可能的生物能量来源,判别其使用价值,尤其是潜在价值。通过各种化学方法或手段转化为可持续资源、能源,如浒苔液化、镁盐晶须、人工海水等。针对当前环境氮、硫污染问题,从源头出发,开展气体、液体的除氮、脱硫工艺研究。
% c) T3 ~$ X# o5 i (四)、微生物化学:通过分析海洋来源微生物群落结构、功能基因、次级代谢产物以及中间产物来探索小分子活性物质的生物合成途径、机理,进一步确定元素迁移路径和能量的转化方式,同时探索发现活性天然产物。通过特殊环境来源微生物的驯化,探索微生物在污染物的去除、降解方面的应用。
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课题组重要成果
! _2 d6 O# l* M! Y$ J 1)Chanjuan Li, Dahai Zhang, Jialin Peng, Xianguo Li*.The effect of pH, nitrate, iron (III) and bicarbonate on photodegradation of oxytetracycline in aqueous solution. Journal of Photochemistry and Photobiology A: Chemistry, 2018, 356: 239–247. # L2 M! ? L. M' F3 b" ?& A7 y
2)Yanxia Lin, Wei Deng*, Shengyong Li, Jiafu Li, Guoguang Wang, Dahai Zhang, Xianguo Li*. Congener profile, distribution, sources and ecological risk of parent and alkyl-PAHs in surface sediments of Southern Yellow Sea, China. Science of the Total Environment, 2017, 580: 1309–1317.
9 @0 X& s0 j0 S4 t& K7 G 3)Guoguang Wang, Jialin Peng, Ting Hao, Yao Liu, Dahai Zhang, Xianguo Li*. Distribution and region-specific sources of Dechlorane Plus in marine sediments from the coastal East China Sea. Science of the Total Environment, 2016, 573: 389–396. 6 }# a* `3 B2 t- W) E- v
4)Guoguang Wang, Jialin Peng, Dahai Zhang, Xianguo Li*. Characterizing distributions, composition profiles, sources and potential health risk of polybrominated diphenyl ethers (PBDEs) in the coastal sediments from East China Sea. Environmental Pollution, 2016, 213: 468-481.
+ Q3 O, K0 Y% [& F1 ~: } 5)Guoguang Wang, Jialin Peng, Xiang Xu, Dahai Zhang, Xianguo Li*. Polybrominated diphenyl ethers in sediments from the Southern Yellow Sea: Concentration, composition profile, source identification and mass inventory. Chemosphere, 2016, 144: 2097-2105.
( K) I; {" Y* @$ c. r! V 6)Jiafu Li, Han Dong, Xiang Xu, Bin Han, Xianguo Li*, Chenjian Zhu, Chen Han, Shaopeng Liu, Dandan Yang, Qian Xu, Dahai Zhang*. Prediction of the bioaccumulation of PAHs in surface sediments of Bohai Sea, China and quantitative assessment of the related toxicity and health risk to humans. Marine Pollution Bulletin, 2016, 104: 92-100.
+ c) o: `% N+ C" S4 e 7)Jialin Peng, Guoguang Wang, Dahai Zhang, Dongmei Zhang, Xianguo Li*. Photodegradation of nonylphenol in aqueous solution by simulated solar UV-irradiation: The comprehensive effect of nitrate, ferric ion and bicarbonate. Journal of Photochemistry and Photobiology A: Chemistry, 2016, 326: 9–15. ! M3 d( P/ P W2 f
8)Yan Zhang, Ying Liu, Han Dong, Xianguo Li, Dahai Zhang*. The nonylphenol biodegradation study by estuary sediment-derived fungus Penicillium simplicissimum. Environmental Science and Pollution Research, 2016, 23(15): 15122–15132.
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课题组照片     4 J; J1 `; h+ ?* E
编辑丨王林项 9 T8 I$ _& v& o& I) X* r
审核丨所芳屹
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