4 B% O( b& H2 q4 V G& U2 M: E( ] 海洋有机地球化学实验室II
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: u# k4 S6 u9 O/ P/ f1 Q, L9 C% q 课题组负责人及老师介绍： * b' k% d' H" t" J) K) q
李先国 教授，博士生导师
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冯丽娟教授，硕士生导师
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0 h; C6 N$ A& N( S- j 张大海 副教授，硕士生导师
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* T+ c' c! m, r; s6 ^ 姚硕 讲师
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9 N# N) {+ J( S0 z 课题组研究领域与方向 . X6 ?! Q2 x4 O$ i, i
目前课题组主要开展四个方向的研究，分别是：
2 ?% P9 F x$ d5 u9 H) A$ G) l, K （一）、陆源有机物及其沉积记录：以木质素、正构烷烃、脂质等为特征生物标志物，研究其在海洋中的沉积记录及其环境地球化学意义。 - i, j4 n2 s |+ v4 y$ Y; v/ x
（二）、现代有机污染物及其转化机理：通过实验室模拟实验中降解中间产物或/和代谢产物的分析、稳定同位素分馏效应的测定以及理论计算，与现场测定结果相结合，研究典型有机污染物在环境中的来源、分布及其光降解和生物降解机理，结合定量构效关系研究，评价其生态风险。目前已经开展的污染物研究包括多环芳烃（PAH）、多氯联苯（PCB）、多溴联苯醚（PBDE）、德克隆（DP）、塑化剂（PAES）、烷基酚（NP和OP）、微塑料（MP）等。 ! X' e" V. z& t/ y% h2 w6 M
（三）：海洋资源化学：通过分析海洋来源物质的成分、结构，确定其可能的生物能量来源，判别其使用价值，尤其是潜在价值。通过各种化学方法或手段转化为可持续资源、能源，如浒苔液化、镁盐晶须、人工海水等。针对当前环境氮、硫污染问题，从源头出发，开展气体、液体的除氮、脱硫工艺研究。
3 L8 u; g% m+ l) D+ G) o' E （四）、微生物化学：通过分析海洋来源微生物群落结构、功能基因、次级代谢产物以及中间产物来探索小分子活性物质的生物合成途径、机理，进一步确定元素迁移路径和能量的转化方式，同时探索发现活性天然产物。通过特殊环境来源微生物的驯化，探索微生物在污染物的去除、降解方面的应用。
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3 m) `0 H3 I6 y7 U- {- L$ V# p4 m 课题组重要成果 ) ?8 t5 |1 M. ^
1)Chanjuan Li, Dahai Zhang, Jialin Peng, Xianguo Li*.The effect of pH, nitrate, iron (III) and bicarbonate on photodegradation of oxytetracycline in aqueous solution. Journal of Photochemistry and Photobiology A: Chemistry, 2018, 356: 239–247. # a0 m& h6 R N8 p0 }3 n
2)Yanxia Lin, Wei Deng*, Shengyong Li, Jiafu Li, Guoguang Wang, Dahai Zhang, Xianguo Li*. Congener profile, distribution, sources and ecological risk of parent and alkyl-PAHs in surface sediments of Southern Yellow Sea, China. Science of the Total Environment, 2017, 580: 1309–1317. * E1 q6 K/ b" ~
3)Guoguang Wang, Jialin Peng, Ting Hao, Yao Liu, Dahai Zhang, Xianguo Li*. Distribution and region-specific sources of Dechlorane Plus in marine sediments from the coastal East China Sea. Science of the Total Environment, 2016, 573: 389–396. / a( R g5 a3 H- ~
4)Guoguang Wang, Jialin Peng, Dahai Zhang, Xianguo Li*. Characterizing distributions, composition profiles, sources and potential health risk of polybrominated diphenyl ethers (PBDEs) in the coastal sediments from East China Sea. Environmental Pollution, 2016, 213: 468-481.
1 B- K3 u& l! z9 F# ]; _5 P% ] 5)Guoguang Wang, Jialin Peng, Xiang Xu, Dahai Zhang, Xianguo Li*. Polybrominated diphenyl ethers in sediments from the Southern Yellow Sea: Concentration, composition profile, source identification and mass inventory. Chemosphere, 2016, 144: 2097-2105. - m0 _( d" C: P( E
6)Jiafu Li, Han Dong, Xiang Xu, Bin Han, Xianguo Li*, Chenjian Zhu, Chen Han, Shaopeng Liu, Dandan Yang, Qian Xu, Dahai Zhang*. Prediction of the bioaccumulation of PAHs in surface sediments of Bohai Sea, China and quantitative assessment of the related toxicity and health risk to humans. Marine Pollution Bulletin, 2016, 104: 92-100.
9 t' z! v% b6 l! y+ K& l 7)Jialin Peng, Guoguang Wang, Dahai Zhang, Dongmei Zhang, Xianguo Li*. Photodegradation of nonylphenol in aqueous solution by simulated solar UV-irradiation: The comprehensive effect of nitrate, ferric ion and bicarbonate. Journal of Photochemistry and Photobiology A: Chemistry, 2016, 326: 9–15. , }! R! C6 E' `& C
8)Yan Zhang, Ying Liu, Han Dong, Xianguo Li, Dahai Zhang*. The nonylphenol biodegradation study by estuary sediment-derived fungus Penicillium simplicissimum. Environmental Science and Pollution Research, 2016, 23(15): 15122–15132.
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, E9 W$ c6 |! j* r 课题组照片   
* |4 B' o0 b$ Q1 Y 编辑丨王林项
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